Photoxidant pollutants


A number of man made pollutants, as nitrogen oxides and volatile organic compounds (VOC), that can affect the photochemical activity, are emitted into atmosphere. Nitrogen oxides are emitted mainly from combustion processes from both mobile sources (e.g. road traffic) or stationary sources (e.g. power plants). VOC are emitted from combustion and also by evaporation of fuels and solvents. Furthermore natural emissions, in particular of hydrocarbon from trees, will also contribute to the photochemical activity.

In the atmosphere these pollutants may react, producing other toxic pollutants (mainly ozone). The production of ozone require sunlight. Therefore ozone above what is considered harmful for the environment or for humans is mostly a problem in the summer months. Both observations and calculations have shown that ozone has increased on a local and regional scale in the European boundary layer. Furthermore, ozone has increased by approximately a factor of two throughout the lower atmosphere in the northern mid latitudes since early this century.
Exceedances of ozone considered harmful for humans and for the environment is most frequent in central and southern parts of Europe. Close to the surface nitrogen oxidants, hydrocarbons and ozone itself can build up in what is called ozone episodes. In northern parts of Europe exceedances are not as frequent mainly because the solar radiation is weaker further north. Both measurements and models show that there has been a reduction in the magnitude of such ozone events in Europe since the late 1980's as a result of emission reductions of ozone precursors over the same period.

To avoid such pollution events emissions must be further reduced. However the chemical mechanisms involved are complicated and there are still uncertainties as to how reductions should be made cost effective (The maximum amount of reductions for a given sum of money). In particular for nitrogen oxides reductions are desirable also for other environmental reasons as acidification and eutrophication.

 

Emissions

The UNECE/EMEP emission database WebDab has been constructed in purpose to facilitate the access to the emission data reported to the Convention on Long-Range Transboundary Air Pollution (CLRTAP) on Main Pollutants among other compounds.

Contact: emep.emissions@umweltbundesamt.at

Measurements

Measurement data is available for all EMEP stations.

Contact person: anne-gunn.hjellbrekke(@)nilu.no

Model descriptions

In 1989, the MSC-W of EMEP began the work on the development of an ozone model of adressing both the problem of short-term episodic ozone and long-term (growing season) ozone. The model was called in the beginning the Lagrangian Ozone model and is also known as the Lagrangian Photooxidant model.
In 1997 results from the EMEP Eulerian photooxidant model were presented for the first time.
But this model has been revised and is documented in EMEP Status Report 1/03 Part I (available at: common EMEP publications) and from 2003 the operational runs are done with Unified EMEP model.

Contact persons: jan.eiof.jonson(@)met.no and david.simpson(@)met.no

Model results

Modelled air concentration and deposition data are downloadable as ASCII files covering the whole EMEP grid. Source-receptor relationships by country of Sulphur and Nitrogen are downloadable as ASCII files, but also overview tables of Sulphur and Nitrogen are available.

Contact: emep.mscw@met.no


Last update: 2009-04-17